Copper-Catalyzed Aerobic Oxidative Rearrangement of Tertiary Allylic Alcohols Mediated by TEMPO
Synlett
DOI: 10.1055/s-0029-1217545
Abstract
A mild method for the oxidative rearrangement of tertiary allylic
alcohols to β-substituted enones using a TEMPO/CuCl system,
in the presence of molecular sieves, is described. Depending on
the substrate, CuCl was used in either a catalytic amount
under an oxygen atmosphere or stoichiometrically.
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© Georg Thieme Verlag Stuttgart ˙ New York
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